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High-Pressure Stopped-Flow Study of Kinetics and Mechanism for Complex Formation Reactions of Tetraaquapalladium(II) and -Platinum(II) with Thioethers in Aqueous Solution

Complex formation between Pd(H2O)42+ and Pt(H2O)42+ and the thioethers Me2S, Et2S, 1,4-dithiane, and 1,4-thioxane has been studied as a function of temperature (278-308 K) and pressure (0.1-200 MPa) by use of stopped-flow and conventional spectrophotometry in an aqueous 1.00 M perchloric acid medium. The rate constants k1 for complex formation are similar for the four thioethers, varying only betw

Limiting costs or correcting market failures? : Finance ministries and frame alignment in UN climate finance negotiations

Finance ministries are increasingly involved in UN climate finance negotiations,yet this development received very limited attention in the literature on climate finance or climate negotiations. It is not obvious from the literature on bureaucratic politics how these ministries will position themselves on climate finance: they may frame climate finance as expenditure to be limited or as an instrum

Business simulation exercises in small business management education : using principles and ideas from action learning

Recent calls to close the rigour-relevance gap in business school education have suggested incorporating principles and ideas from action learning in small business management education. In this paper we discuss how business simulation exercises can be used as a platform to trigger students’ learning by providing them with a platform where they can merge theory with practice. We provide theoretica

Entrepreneurs’ attitudes towards failure : an experiential learning approach

Purpose– This paper employs theories of experiential learning to examine why some entrepreneurs have developed a more positive attitude towards failures compared to others.Design/methodology/approach– The paper conducts statistical analysis on a sample of 231 Swedish entrepreneurs that have started new independent firms in 2004.Findings– The empirical findings support the guiding proposition that

Business angels and value added : what do we know and where do we go?

Business angels have been highlighted as important stakeholders for potential high-growth ventures. Extant empirical research provides evidence that they not only contribute with money but also bring added value to the ventures in which they have invested. However, despite the reported benefits of the value added provided by these investors there are very few studies that try to conceptualize this

Gene therapy : Therapeutic gene causing lymphoma

The development of T-cell leukaemia following the otherwise successful treatment of three patients with X-linked severe combined immune deficiency (X-SCID) in gene-therapy trials using haematopoietic stem cells has led to a re-evaluation of this approach. Using a mouse model for gene therapy of X-SCID, we find that the corrective therapeutic gene IL2RG itself can act as a contributor to the genesi

VESPA : The vibrational spectrometer for the European Spallation Source

VESPA, Vibrational Excitation Spectrometer with Pyrolytic-graphite Analysers, aims to probe molecular excitations via inelastic neutron scattering. It is a thermal high resolution inverted geometry time-of-flight instrument designed to maximise the use of the long pulse of the European Spallation Source. The wavelength frame multiplication technique was applied to provide simultaneously a broad dy

Intersectionality and risk for ischemic heart disease in Sweden: Categorical and anti-categorical approaches

Intersectionality theory can contribute to epidemiology and public health by furthering understanding of power dynamics driving production of health disparities, and increasing knowledge about heterogeneities within, and overlap between, social categories. Drawing on McCall, we relate the first of these potential contributions to categorical intersectionality and the second to anti-categorical int

The impact of CEO long-term equity-based compensation incentives on economic growth in collectivist versus individualist countries

This study examines the impact of the prevalence of long-term equity-based chief executive officer (CEO) compensation incentives on GDP growth, and we address the moderating role of individualist versus collectivist cultures on this relationship. We argue that long-term incentives given to CEOs in some firms may convey to other CEOs that they too may be able to receive such incentives and rewards

Marine ecosystem connectivity mediated by migrant–resident interactions and the concomitant cross-system flux of lipids

Accumulating research argues that migrants influence the functioning and productivity of local habitats and ecosystems along migration routes and potentially drive cross-system energy fluxes of considerable magnitude, yet empirical documentation of local ecological effects and descriptions of the underlying mechanisms are surprisingly rare. In this study, we discovered migrant–resident interaction

On connection control and traffic optimisation in FMC networks

With the introduction of smartphones and tablets and the dramatical increase of the data traffic on the cellular network, operators are seeking for new solutions to provide the users with continuous connectivity while preserving a good quality of service. Since most of current user terminals are equipped with multiple interfaces, one solution is to take advantage of the different access networks.

A to Z of the muon anomalous magnetic moment in the MSSM with Pati-Salam at the GUT scale

We analyse the low energy predictions of the minimal supersymmetric standard model (MSSM) arising from a GUT scale Pati-Salam gauge group further constrained by an A4 × Z5 family symmetry, resulting in four soft scalar masses at the GUT scale: one left-handed soft mass m0 and three right-handed soft masses m1, m2, m3, one for each generation. We demonstrate that this model, which was initially dev

Care and services at home for persons with dementia. Structure, process, and outcomes.

The overall aim of this thesis was to investigate formal care and services at home, regarding structure, process, and outcomes, for persons with dementia (aged 65+ years) at risk of nursing home admission. Availability and utilization of formal care and services at home for persons with dementia, from diagnosis to end-of-life stage, in eight European countries was described in study I. A mapping f

Mid-infrared pumped laser-induced thermal grating spectroscopy for detection of acetylene in the visible spectral range

We present mid-infrared laser-induced thermal grating spectroscopy (IR-LITGS) using excitation radiation around 3 μm generated by a simple broadband optical parametric oscillator (OPO). Acetylene as a typical small hydrocarbon molecule is used as an example target species. A mid-infrared broadband OPO pumped by the fundamental output of a neodymium-doped yttrium aluminum garnet (Nd:YAG) laser was

Nurses' attitudes to the use of alternative medicine in cancer patients

This study reports results from a questionnaire study on nurses' attitudes to and experiences with alternative medicine, especially related to cancer patients' use of alternative medicine. Sixty nurses from a department of oncology and haematology participated in the study. The response rate was 62%. The nurses primarily perceived the use of alternative medicine as an individual choice which the n