Photoinduced Charge Carrier Dynamics of Zn-Porphyrin-TiO(2) Electrodes: The Key Role of Charge Recombination for Solar Cell Performance (†).
Time resolved absorption spectroscopy has been used to study photoinduced electron injection and charge recombination in Zn-porphyrin sensitized nanostructured TiO(2) electrodes. The electron transfer dynamics is correlated to the performance of dye sensitized solar cells based on the same electrodes. We find that the dye/semiconductor binding can be described with a heterogeneous geometry where t