Cascade catalysis of highly active bimetallic Au/Pd nanoclusters: structure-function relationship investigation using anomalous small-angle X-ray scattering and UV-Vis spectroscopy
Recently, a so-called 'crown-jewel' concept of preparation of Au/Pd-based colloidal nanoclusters has been reported [Zhang, Watanabe, Okumura, Haruta & Toshima (2011). Nat. Mater. 11, 49-52]. Here, a different way of preparing highly active Au/Pd-based nanoclusters is presented. The origin of the increased activity of Au/Pd-based colloidal bimetallic nanoclusters was unclear up to now. However,