Reactivity of the unsaturated triosmium cluster Os-3(CO)(8)(mu(3)-eta(2)-Ph2PCH2P(Ph)C6H4)(mu-H) with benzothiophene: Activation of a P-C bond in diphosphine and a C-H bond in benzothiophene
Treatment of the electronically unsaturated cluster Os-3(CO)(8)(mu(3)-eta(2)-Ph2PCH2P(Ph)C6H4)(mu-H) (1) with benzothiophene in refluxing m-xylene afforded Os-3(CO)(7)(mu-PPh2)(mu-PMePh)(mu(3)-eta(2)-C6H4) (2), Os-3(CO)(7)(mu(3)-eta(2)-PPh(C6H4)CH2PPh)(mu(3)-eta(3)-SC8H5)(mu-H) (3), and Os-3(CO)(8)(mu-CO)(mu(3)-eta(2)-PPh(C6H4)CH2PPh) (4). Thermolysis of 1 in refluxing toluene for 35 h afforded on
