Synthesis of New Thiol Derivatives of Os3(CO)12; Crystal Structure of HOs3(CO)10(SBut)
The clusters [Os3(CO) 10(/z-H) {/z-SC(CH3)3} ] (1) and [Os3(CO) to(/z-H) {p-SCeHH } ] (2) have been synthesized by addition of the appropriate thiol RSH (R ffi C(CH3)3, CeHH) to [Os3(CO) it (NCMe) ] or [Os3(CO) io(NCMe)2] in dichloromethane. Clusters 1 and 2 have been characterized by 1R, NMR, mass speetromet~, and, in the case of 1, X-ray crystallography. Compound I crystallizes in space group P2