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The cyclometallated dinuclear (2-phenyl-pyridine) palladium acetate and chloride [{PdCl(phpy)}(2)] and [{PdOAc(phpy)}(2)] were reacted with potentially bridging N- and S-donor ligands. The N,N-ligands bind with only one nitrogen and form monomeric products. The S,S-ligand binds in a chelate mode, also forming a monomeric complex. 3,3-Dimethyl glutarate, on the other hand, binds in a bridging mode.
