Nanoscopic properties of silica filled polydimethylsiloxane by means of positron annihilation lifetime spectroscopy
Positron annihilation lifetime spectroscopy (PALS) was performed on a series of polydimethylsiloxane (PDMS)/fumed silicon dioxide (SiO2) composites at temperatures between -185 and 100degreesC to study the effect of filler content and filler particle size on the free volume properties and the positron annihilation characteristics. The glass transition behavior of the PDMS/SiO2 composites was deter