Operando study of Ni-22Cr oxidation dynamics with nanoscale resolution in an X-ray photoemission electron microscope
Understanding the initial oxidation pathways on binary Ni-Cr surfaces is import for alloy development and rational design. The early-stage oxidation of Ni-22wt% Cr is studied in-situ and in-operando with synchrotron-based x-ray photoelectron microscopy (XPEEM) and x-ray photoelectron spectroscopy (XPS) at 500 °C and oxygen exposure from 0 to 65 Langmuir. Preferential Cr oxidation is accompanied by