Conflict between the Electronic Factors and Structure-Directing Rules in the Intergrowth Structure of Ca4Ag2+xGe4-x with x = 1/2
Combined experimental and theoretical efforts to conceptually understand the structure directing forces in intergrowth structures have led to the discovery of the new ternary phase Ca4Ag2+xGe4-x (x = 0.5), obtained from high-temperature reaction of the elements. It crystallizes in a new structure type according to single-crystal diffraction methods: monoclinic space group C2/m-i10 with a = 10.7516
