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Point defects in titanium dioxide (TiO2) are the most relevant reaction sites for the activation of oxygenates. Herein, we probe the activation of CO2 on highly defective TiO2 in situ using synchrotron-based near-ambient pressure X-ray photoelectron spectroscopy between 0.1 mbar and 2.6 mbar from room temperature to 700 K. Multiple carbon surface intermediates form upon CO2 activation. The presenc
