Directly measuring reaction kinetics of (center dot)QOOH - a crucial but elusive intermediate in hydrocarbon autoignition
Hydrocarbon autoignition has long been an area of intense fundamental chemical interest, and is a key technological process for emerging clean and efficient combustion strategies. Carbon-centered radicals containing an -OOH group, commonly denoted (center dot)QOOH radicals, are produced by isomerization of the alkylperoxy radicals that are formed in the first stages of oxidation. These (center dot