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Treatment of [(mu-H)Os-3(CO)(10)(mu-OMe)] (1) with dppm {dppm = bis(diphenylphosphino)methane} at 110 degrees C gave the known compound [Os-3(CO)(10)(mu(2)-eta(2)-dppm)] (2) and the new compound [(mu-H)Os-3(CO)(8)(mu-OMe)(mu(2)-eta(2)-dppm)] (3). A similar reaction of 1 with dppe {dppe=bis(diphenylphosphino)ethane} afforded two products, [(mu-H)Os-3(CO)(8)(mu-OMe)(mu(1)-eta(2)-dppe)] (5) and [(mu-
