Functionalizing polystyrene with N-alicyclic piperidine-based cations via Friedel-Crafts alkylation for highly alkali-stable anion-exchange membranes
Different anion-exchange membranes (AEMs) based on polystyrene (PS) carrying benzyltrimethyl ammonium cations are currently developed for use in alkaline fuel cells and water electrolyzers. However, the stability of these state-of-the-art cations needs to be further improved. Here, we introduce highly alkali-stable mono- and spirocyclic piperidine-based cations onto PS by first performing a supera