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There has been active research in the development of new rigid biobased aromatic dicarboxylate monomers that can replace the widely used fossil-based dimethyl terephthalate in polyester production. In this work, a new biobased dicarboxylate monomer with a spiroacetal unit was synthesized from biobased vanillin and pentaerythritol, which aims to partially or completely replace the fossil-based
