Continuous Flow Dehydrogenation of Isopropanol by Heterogenized Ir-POCOP Pincer Catalysts
Supported Iridium pincer complexes were used to study gas-phase isopropanol dehydrogenation under continuous flow system at temperatures 200-260 °C with different flow rates. First supported catalyst was [Ir(C2H4)(p-tBu2PO-tBu4POCOP)] supported by covalent bonding to silica, the second one was [Ir(HCl)(p-HO2C- tBu4POCOP)] supported by adsorption to γ-Alumina. The highest activity of catalyst 1 w