Structure of highly concentrated aqueous electrolyte solutions of transition metal chlorides and bromides
The structures of the complexes dominating in highly concentrated and 1.0 mol dm−3 aqueous solutions of first-row transition metal chlorides and bromides have been studied using large angle X-ray scattering (LAXS) and/or EXAFS. Of these systems, only zinc(ii) chloride and bromide form inner-sphere complexes in dilute aqueous solutions. No inner-sphere complexes corresponding to dilute aqueous perc
