Nucleation-limited composition of ternary III-V nanowires forming from quaternary gold based liquid alloys
We derive an analytic expression for the composition of a ternary solid material nucleating from a quaternary liquid melt. The calculations are based on the two-component nucleation theory with realistic descriptions of the liquid and solid phases. We apply this theory to gold-catalyzed, nucleation limited vapor-liquid-solid growth of ternary III-V nanowires. We consider ternary gallium, indium, a