Adsorption of oxalate and malonate at the water-goethite interface: molecular surface speciation from IR spectroscopy
The adsorption of oxalate and malonate at the water-geothite interface was studied as a function of pH and total ligand concentrations by means of quantitative adsorption measurements and attenuated total reflectance Fourier transform infrared spectroscopy. The obtained results conclusively showed that oxalate and malonate both form outer-sphere and inner-sphere surface complexes on goethite, and