Two 3D supramolecular architectures from zinc hydrogen aconitate 1D polymers
The reaction of Zn(NO3)(2)center dot 3(H2O) with trans-aconitic acid, in presence of chelating Lewis bases, leads to the formation of the 1D polymers [Zn(N-N)(LH)] center dot nH(2)O, where LH3 = trans-aconitic acid, 1 : N-N = 1,10-phenanthroline (phen), n = 1, 2 : N-N = 2,2'-bipyridine (bpy), n = 2. 3D supramolecular assemblies are constructed through H-bonding and stacking interactions. (C) 2006